Actually, it's not a problem. Just make sure the contacts in your Hotmail account are the same as in your Gmail account. When the contacts on your phone sync with Gmail, it will include all contacts there.
So, for example, if you have some contacts that are in Hotmail that aren't in Gmail, add them to Gmail online using your computer, and the next time you sync your Gmail and contacts, they will be synced with the contacts on your phone.
When you go into the Mail app on your phone, choose your Hotmail account, press on the TO field and start typing a contact's name. You should then see their email address in a drop down list so you can select it.
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