Personally I hate iTunes.
However I do not understand as to how WinAmp does not suit your needs. I mean I have WinAmp syncing straight to a music folder I specifically defined in my device. No double twist needed, just straightup WinAmp from PC to phone.
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SugarSync and DropBox Referrals
SugarSync (gives 5gb free on registration)
DropBox (gives 2gb free on registration)
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