OK, take a screenshot whilst in game so you can see the controls on screen. Exit the game, open Sixaxis, then menu > preferences > touch emulation > edit touch profiles > Double tap to bring up the menu > Change background and add your screenshot. You might Need to rotate the screenshot, but once you have, click add button and you'll be presented with a list of controller buttons. Line them up with the on screen controls, save the profile and you're done.
When you want to play that game, open sixaxis, pair, then load that games profile.
Have you tried all that?