As promised, here are a couple of tips to start out with your battery correctly. Keep in mind that Lithium based batteries do not need break in. However, they should be drained and charged to 100% once to calibrate the digital sensor.
So, here is what I do when I get a new battery:
-It usually comes at about 40% (the optimal storage charge for Lithium batteries), so I drain it. Then charge to 100% (you can use it during this), and discharge to auto off again. Now, the sensor is calibrated.
-from here on out, lithium batteries like small charges instead of total drains. So charge whenever you can. As a note, when the specs say it has a lifetime of 500 cycles. It means 500 0% to 100% cycles. Although the relationship is complex and not totally linear, you can assume that if you charge the battery at the end of the day when it only has 30% left, it is not a full cycle. It is about 70% of a cycle. In the same way, charging from 80% to full is about 20% of a cycle. Not exactly, but good enough of an approximation.
-Every month or so (45 days?), you can recalibrate the sensor by draining until auto off and then charging to 100% and draining again. That way your battery indicator will be as accurate as it can be.
Also, I was PM'ed some questions. Here they are:
What is the difference between a lithium ion and a lithium polymer?
Lithium ion uses an ion soaked porous electrolyte, whereas lithium polymer uses a solid polymer one. Polymer batteries have a very high internal resistance which prevents high currents, and as such are usually soaked with some gel type substance to increase the conductivity. The chemistry (and even physical structure after the gel soaking) of Polymer is very similar to that of Lithium ion.
Polymer batteries are can also be smaller (credit card sized). They are also a lighter weight and more resistant to being overcharged. However, they cost more to make and have a lower lifetime than their ion counterparts.
Do I really need to charge the battery first before I use it the first time?
No. See above. This is an old habit from older battery technologies and chemisries.
I know it was mentioned earlier that the batter does not come partially charged, but I thought this was standard that they did...
It does. At 40%, as stated above. Not fully charged, and they tell you it is not charged so that you do not expect it, but it is. 40% is the best charge to store lithium batteries with.
How do you recommend proper battery calibration?
See above
Also, letting it sit overnight (assuming it gets charged in 2-3 hours) is said to be not good. however, I thought the phone was smart enough to know when the battery is full to discontinue charging, even if connected? Not so?
Modern batteries have circuitry in them to prevent overcharge. Normally they charge to about 4.2 volts per cell. At about 4.3 V/cell, it stops.
There is more in depth stuff to come, but I am currently asking the mods how to handle it. If I go in depth, I feel that that information should be consolidated to the first posts of a thread for easy access. By in depth I mean 6 or more posts going into the chemistry and other things, for those who are interested. It will also include non technical advice. At the same time I do not want to upstage Kappy and this helpful thread he has created. I am also planning another couple of things, but they need community involvement and I am asking for the mods' advice on how to proceed. Look for more useful information in the next couple of weeks and months.
-Nkk