Amperage is the dangerous part, you can touch something thats 10,000 volts but only 1 ampere and probably just feel a tingle, but if you touched something thats only, say, 12 volts (like a car) but like 100 amps, you will get SHOCKED.
Just in case anyone should be tempted to use this information in real life:
Current flow is a function of supply voltage and load resistance, the fact that a supply
can provide 100 A doesn't mean it
will. The resistance between two dry points on a healthy human body varies from a few thousand ohms to 5-7 million depending on a very large number of factors. But for safety's sake, you should assume a lower value. Let's use 25,000.
The USB spec says the DC supply is 5V at up to 500 mA. Into a 25 KΩ (thousands of ohms) load, that's 0.2 mA, which is well below what you'd be able to feel.
12V into 25 KΩ will result in current of 0.00048 A (amperes) or 0.48 mA (milliamperes, or thousandths of an ampere). You're not going to feel that, either.
120V from your wall outlet will be about 5 mA. That's not only going to hurt, you'll have muscle contractions. Or at least that would be the case if it were DC, but it's AC, and the composition of your body results in a much lower effective resistance under those conditions. (Why is a long story.) Take a worst-case of 3 KΩ and you're into about 40 mA, which is well into the range of violent muscle contractions and on the edge of the 50-100 mA range where your heart starts fibrillating. (That, for what it's worth, is the cause of death in most electrocutions.) If your skin is wet, the resistance can be as low as a few hundred ohms, which means even more current flow.
220 V from the wall outlets in most countries (again AC, so we'll use 3 KΩ
is 73 mA, which is fibrillate-and-die territory (50-100 mA).
Coming into contact with a 10,000 V AC supply will get you a nice 3-amp jolt, which is enough to kill you 30 times over. Even if that supply were only capable of delivering 1 A, that's still enough to do you in.
--Mark