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Question: Why does the first 5-10% of battery go so quickly.

I am by no means a programmer, or phone tech compared to anyone. But just taking a guess from a logical point of view I think it would be something like this.

The phone's battery bar shows how much voltage is left. It divides the amount of voltage/energy left into sections (lets call them buckets). These buckets depending upon the battery and software sometimes indicate they are empty once they are only slightly down from full.

That would seem to me why a phone would indicate it is down 2-6% immediately after being taken off the charger is you have taken a "handful" of energy out of the bucket and now since it's not being refilled that indicates it is now a "empty bucket" when it is mostly full. This would also go along with your indicate that it goes down about 4% and then doesn't go down anymore. It could be because that bucket has to be drained for it to remove some from the next bucket (after which only a handful being removed would make another 4% bar change).

I think I read something about this with one of the Android phones but I don't have a link, and I thought it was phone specific but it might have been the EVO. I can't remember :( Hope this helps and don't blame me if I am wrong ;). Maybe someone more knowledgeable will come along and let you know.
 
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Check out eieio's post in the battery section. Not guaranteed to work but some people notice a difference. In a nutshell:

1. Charge phone while on til light is green.

2. WITHOUT unplugging hold power button and choose to shutdown phone. Let charge til green.

3. Power phone back on and etc. etc.

Repeat those steps until there is a 1-2min delay in LED turning from orange/amber to green.

But like I said, eieio posted that in his battery thread if you need it a little more in depth.

P.S. Just looked it up, it's the first sticky on the EVO 4G forums, 'Possible Battery Fix from HTC.

Enjoy!
 
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