I only use the hotmail exchange setup way (I hate the samsung email app and use enhanced email, the best but $10)
I have never had any problems with my hotmail set up this way, but I do have problems with hotmail set up as a pop account.
Now I use my hotmail email for personal and work, I send large files, and receive many in a day, the only problem I get and this is with all phones including the iphone, is in very weak signal areas, if I delete a message, sometimes it does not get deleted on the hotmail server and when I log in with a computer I just delete it, no big deal and only in very poor signal areas.
here is a setup guide for the exchange way
http://androidforums.com/samsung-galaxy-s3/580565-hotmail-enhanced-email-setup-siii-icloud-charter-settings.html