It will depend on your network provider. Most offer several ways: with a number which you can dial to access your balance; by a text message; through registering on their website; via an app you can install on your phone.
Your network provider's website or their customer service line will tell you more.
Who's your current network provider? If there is an app that will look up your account, then it should be available via a link on their website or at Android Market.
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