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Help Can't send mail from pop account...

Try changing your smtp port to 587. That's a stab in the dark, but it might work. ISPs sometimes blocks the standard port 25 to combat spam.

Some ISPs only allow you to send mail if you're connected on their network. If you connect through 3G, you will be sending mail from your cell provider and your ISP may not allow that OR if they allow it they may require authentication.

I believe that a Blackberry doesn't connect directly to your mail server like an Android device does. I think that all email on a Blackberry actually goes through Blackberry's servers. You can achieve a similar effect on Android by having gmail check your other account. Go to the gmail.com web site setting and set it up under Accounts.
 
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